Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]aza-cryptand
CHEMICAL COMMUNICATIONS, sa.8, ss.810-812, 2007 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Basım Tarihi: 2007
- Doi Numarası: 10.1039/b613564a
- Dergi Adı: CHEMICAL COMMUNICATIONS
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.810-812
- Yıldız Teknik Üniversitesi Adresli: Hayır
Özet
A calix[6] arene capped by a tmpa unit provides Cu(II) funnel complexes that, for the first time, accept not only neutral guest ligands but also anionic ones such as a hydroxide, which is due to a small conformational change in the calixarene cone.