Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]aza-cryptand

Izzet G., Zeng X., Akdas H., Marrot J., Reinaud O.

CHEMICAL COMMUNICATIONS, sa.8, ss.810-812, 2007 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1039/b613564a
  • Dergi Adı: CHEMICAL COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.810-812
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

A calix[6] arene capped by a tmpa unit provides Cu(II) funnel complexes that, for the first time, accept not only neutral guest ligands but also anionic ones such as a hydroxide, which is due to a small conformational change in the calixarene cone.