Photopolymerization and photophysical properties of amine linked benzophenone photoinitiator for free radical polymerization

Temel G., Enginol B., AYDIN M., Balta D., ARSU N.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, vol.219, no.1, pp.26-31, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 219 Issue: 1
  • Publication Date: 2011
  • Doi Number: 10.1016/j.jphotochem.2011.01.012
  • Journal Name: JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.26-31
  • Keywords: Benzophenone, Free radical polymerization, Type II system, UV curing, COINITIATOR AMINE, PHOTOCHEMISTRY, INITIATORS, ACID
  • Yıldız Technical University Affiliated: Yes

Abstract

Synthesis of amine linked type II photoinitiator (BPDEA) was achieved in high yields and photopolymerization of mono and multiacrylate monomers was performed with this photoinitiator in the absence of a coinitiator. BPDEA is more effective than benzophenone (BP) with the coinitiator (MDEA) system under inert atmosphere in photoinduced free radical polymerization of acrylates. (C) 2011 Elsevier B.V. All rights reserved.