Simple and Green Vortex-Assisted Switchable Solvent Liquid Phase Microextraction for the Determination of Indium in Soil with Matrix Matching and Slotted Quartz Tube (SQT)–Flame Atomic Absorption Spectrometry (FAAS)
Analytical Letters, cilt.54, ss.1627-1638, 2020 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 54
- Basım Tarihi: 2020
- Doi Numarası: 10.1080/00032719.2020.1818765
- Dergi Adı: Analytical Letters
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
- Sayfa Sayıları: ss.1627-1638
- Anahtar Kelimeler: (E)-2, 4-dibromo-6-(((3-hydroxyphenyl)imino)methyl)phenol, indium, slotted quartz tube - flame atomic absorption spectrometry (SQT-FAAS), soil, switchable solvent-based liquid phase microextraction, EXTRACTION PROCEDURE, PALLADIUM, GALLIUM, SPECTROPHOTOMETRY, PRECONCENTRATION, DESIGN
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
A novel preconcentration methodology to enhance the sensitivity of a flame atomic absorption spectrometer for indium determination was investigated in this study. The proposed methodology is based on the application of switchable solvent based liquid-phase microextraction combined with a slotted quartz tube. The isolation of indium was performed using N, N-dimethylbenzylamine as the extraction solvent after complexation with (E)-2,4-dibromo-6-(((3-hydroxyphenyl)imino)methyl)phenol. The detection power was enhanced by approximately 169-fold using the developed method with respect to the conventional flame atomic absorption spectrometry system. The quantification and detection limit values were 28.3 and 8.4 ng mL(-1), respectively. The assessment of several interfering ions on the analyte was performed, and spike experiments were used to validate the method's accuracy. Interferences were observed for a ratio of 1:10 analyte:interferent with a value of 27%. The recovery results obtained using matrix matching strategy indicated the applicability of the developed method for soil matrices.