Structural and Surface Characterization of Newly Synthesized D-pi-D Type Schiff Base Ligand: (1E,2E)-3-[4-(Dimethylamino)phenyl]prop-2-en-1-ylidene)phenylamine

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Gumrukcu G., Garikyan S., Karaoglan G., Sakar D.

JOURNAL OF CHEMISTRY, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Publication Date: 2013
  • Doi Number: 10.1155/2013/298205
  • Journal Name: JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Yıldız Technical University Affiliated: Yes

Abstract

A new Schiff base with D-pi-D type, (1E,2E)-3-[4-(dimethylamino)phenyl]prop-2-en-1-ylidene)phenylamine, has been successfully synthesized using the reaction of (2E)-3-[4-(dimethylamino)phenyl]acrylaldehyde with aniline. The Schiff base ligand has been characterized by FTIR, UV-visible, and H-1 NMR as well as TG/DTA, SEM, BET, and elemental analyses and mass spectra. Surface properties and acid-base constants of Schiff base ligand were determined by IGC measurements.