The synthesis, characterization, electrochemical and spectroelectrochemical properties of a novel, cationic, water-soluble Zn phthalocyanine with extended conjugation

Karaoglan G., Gumrukcu G., KOCA A., Gül A.

DYES AND PIGMENTS, cilt.88, sa.3, ss.247-256, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 88 Sayı: 3
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.dyepig.2010.07.003
  • Dergi Adı: DYES AND PIGMENTS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.247-256
  • Anahtar Kelimeler: Phthalocyanine, Zinc, Schiff base, Quaternization, Spectroelectrochemistry, Extended conjugation, NONLINEAR-OPTICAL-PROPERTIES, METAL-CONTAINING PHTHALOCYANINES, IN-SITU, COMPLEXES, BEHAVIOR, METALLOPHTHALOCYANINES, DERIVATIVES, POLYMERS, BEARING, IODINE
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A novel Zn phthalocyanine substituted with four dimethylaminocinnamaldiminophenyloxy substituents at peripheral positions was obtained by the condensation of various 4'-aminophenoxy substituted phthalocyanines and 4-(dimethylamino)cinnamaldehyde Quaternization of the dimethylamino functionality produced cationic Zn phthalocyanines which were soluble in both water and other polar solvents such as methanol and DMSO The novel compounds were characterized using elemental analysis IR H-1 NMR UV-Vis and MALDI-TOF MS spectral data Electrochemical in situ spectroelectrochemical and in situ electrocolorimetric measurements revealed that the complexes undergo electron transfer reactions via the nitro and amine groups in addition to common Pc ring-based processes (C) 2010 Elsevier Ltd All rights reserved