Synthesis and characterization of a Ni(II) and Cu(I) complexes of Schiff base derived from salicylaldehyde

DEMİRHAN N., KARAOGLAN G., AYDIN S.

ASIAN JOURNAL OF CHEMISTRY, cilt.20, sa.3, ss.2367-2372, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20 Sayı: 3
  • Basım Tarihi: 2008
  • Dergi Adı: ASIAN JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2367-2372
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A new Schiff-base ligand, 2-(3-[2-(6-aminoquino[8,7-b]azin-5-yliminomethyl) phenoxy]propoxy)-benzaldehyde has been synthesized from the reaction of 1,5-bis(2'-formylphenyl)-1,5-dioxapentane with 5,6-diamino-1,10-phenanthrol ine and its metal complexes with Cu(I) and Ni(II) have been prepared. Molecular structure of Schiff-base and its metal complexes have been investigated and characterized by FT-IR, H-1 NMR, C-13 NMR, fluorescence, FAB (+) mass spectra, elemental analysis, magnetic measurements and TGA-DSC-DTG techniques.