SYNTHESIS AND THERMAL PROPERTIES OF NOVEL MALEONITRILES


ERDOĞMUŞ A.

SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI, cilt.34, ss.153-158, 2016

  • Cilt numarası: 34 Konu: 2
  • Basım Tarihi: 2016
  • Dergi Adı: SIGMA JOURNAL OF ENGINEERING AND NATURAL SCIENCES-SIGMA MUHENDISLIK VE FEN BILIMLERI DERGISI
  • Sayfa Sayısı: ss.153-158

Özet

In this study, the synthesis and thermal properties of two novel maleonitriles bearing 8-membered heterocyclic derivatives is described first time. New maleonitriles, benzo-(1,2-bis-methylthio) maleonitrile and [Benzo-15-crown-5]-(4,5-bis-methylthio) maleonitrile have been prepared by the reaction of different alkyl halides such as 1,2-bis(brommethyl) benzene and 4,5-bis-(brommethyl)[benzo-15-crown-5] with dithiomaleonitrile disodium salt. Both compounds are characterized by IR, Mass, NMR spectroscopy as well as elemental analysis.