The reaction of <i>N</i>-dichlorophosphoryl-<i>P</i>-trichlorophosphazene with alkyl Grignard reagents

ASLAN F., ÖZTÜRK A. İ., ARSLAN M.

HETEROATOM CHEMISTRY, cilt.14, sa.5, ss.413-416, 2003 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 14 Sayı: 5
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1002/hc.10153
  • Dergi Adı: HETEROATOM CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.413-416
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene Cl3P=N-P(O)Cl-2 (1) with benzylmagnesium bromide, 2-phenylethylmagnesium bromide, trimethylsilylmethylmagnesium chloride, n-butylmagnesium bromide, cyclopentylmagnesium bromide, cyclopentylmagnesium bromide, tert-butylmagnesium bromide, iso-propylmagnesium bromide, and ethylmagnesium bromide were studied. Tri- and pentaalkyl phosphazenes were obtained in very poor yield from trimethylsilylmethylmagnesium chloride and cyclohexylmagnesium bromide, respectively. Tri-alkylphosphoryl compounds formed from benzyl-, 2-phenylethyl-, and n-butylmagnesium bromide. No phosphorus compound could be isolated from the reaction of I with t-butyl-, cyclopentyl-, iso-propyl-, and ethylmagnesium bromide. (C) 2003 Wiley Periodicals, Inc.