Molecular tectonics: design, synthesis and structural analysis of thiacalixarene-based tectons
COMPTES RENDUS CHIMIE, cilt.6, sa.5-6, ss.565-572, 2003 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 6 Sayı: 5-6
- Basım Tarihi: 2003
- Doi Numarası: 10.1016/s1631-0748(03)00089-4
- Dergi Adı: COMPTES RENDUS CHIMIE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.565-572
- Anahtar Kelimeler: calix, pyridine, thiacalix, tecton, ligand, structure, COORDINATION NETWORKS, SILVER CATION, CALIXARENES, LIGANDS, P-TERT-BUTYLTHIACALIX<4>ARENE, PORPHYRINS, CHEMISTRY, ISOMERS, SULFUR, COPPER
- Yıldız Teknik Üniversitesi Adresli: Hayır
Özet
The synthesis of five new coordinating tectons based on tetrathiacalix[4]arene backbone was achieved and their structure analysed and confirmed by X-ray diffraction on single crystal. All tectons were based on tetrafunctionalisation of either tetrathiacalix[4]arene or tetramercaptotetrathiacalix[4]arene derivatives by four pyridine units. The junction between the pyridine units and the calix backbone was ensured by ester or thioester groups. On the pyridine ring, either position 3 or 4, defining the location of the coordination sites, were used to connect the monodentate site to the calix framework.