Sensitive Determination of 4-n-Nonylphenol in Domestic Wastewater and Liquid Detergent by Binary Solvent Microextraction (BSME) and Gas Chromatography–Mass Spectrometry (GC-MS) with Matrix Matching Calibration

Erarpat S., Bodur S., Chormey D. S., Öz E., Bakırdere S.

Analytical Letters, cilt.55, sa.7, ss.1080-1092, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 55 Sayı: 7
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1080/00032719.2021.1985511
  • Dergi Adı: Analytical Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1080-1092
  • Anahtar Kelimeler: 4-n-nonylphenol, binary solvent microextraction (BSME), environmental chemistry, gas chromatography-mass spectrometry (GC-MS), water quality, SOLID-PHASE MICROEXTRACTION, BISPHENOL-A, NONYLPHENOL, PESTICIDES, SAMPLES, DESIGN, RIVER
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

© 2021 Taylor & Francis Group, LLC.Binary solvent microextraction (BSME) coupled to gas chromatography–mass spectrometry (GC-MS) was employed to determine 4-n-nonylphenol in domestic wastewater and detergent. The developed BSME method was applied to obtain lower detection limits by preconcentrating the analyte before determination by GC-MS. Relevant parameters of the extraction method, including the binary solvent volume, dispersive solvent volume, and vortex period, were optimized using Box-Behnken Design. Under the optimum conditions, the limit of detection (LOD), limit of quantitation, and linear dynamic range were 0.6, 2.0, and 2.0 to 100 ng g−1, respectively. The extraction procedure provided an approximate 470-fold enhancement in the detection power. Recovery experiments were performed for spiked wastewater and detergent by performing matrix matching calibration. The recoveries obtained by BSME-GC-MS for wastewater and detergent were between 94 and 103% and 91 and 109%, respectively.