Variables affecting the yields of methyl esters derived from in situ esterification of rice bran oil


Ozgul-Yucel S., TURKAY S.

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, cilt.79, sa.6, ss.611-614, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 79 Sayı: 6
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1007/s11746-002-0531-5
  • Dergi Adı: JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.611-614
  • Anahtar Kelimeler: esterification, fatty acid, fatty acid methyl esters, in situ esterification, rice bran, rice bran oil, TRANS-ESTERIFICATION, SEED OIL, INSITU
  • Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The influence of specific factors on in situ methanolic esterification of rice bran oil (RBO) using sulfuric acid catalyst was investigated. Using high-FFA rice bran was found to be the most effective means to increase methyl ester yields. The ester content of the extract increased about 67% when the FFA content of oil was increased from 16.6 to 84.5%. Increasing the reaction time beyond 30 min did not affect yields. Increasing the temperature from 20 to 65degreesC elevated the FAME yield by about 30%, but increasing the amount of acid catalyst above 5 mL did not enhance yield, and increasing the methanol dose from 200 to 250 mL had a negligible effect.