Synthesis, spectral and thermal characterization, biological activity of a new amino acide ester containing substituted salicylaldimine Schiff base ligand and its Ru(II)bipyridyl complex

Yorur-Goreci C., Altas-Puntar N., Toraman A., DEMİRHAN N.

MAIN GROUP CHEMISTRY, cilt.20, sa.2, ss.193-202, 2021 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 20 Sayı: 2
  • Basım Tarihi: 2021
  • Doi Numarası: 10.3233/mgc-210032
  • Dergi Adı: MAIN GROUP CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Chemical Abstracts Core, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.193-202
  • Anahtar Kelimeler: Amino acid ester, antifungal agent, fluorescence spectroscopy, ruthenium complex, METAL-COMPLEXES, CONDENSATION, FLUORESCENCE, DERIVATIVES, SULFUR
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

The new salicylaldimine, as O,N-bidentate ligand (HL), containing amino acide ester and its Ru(II) complex [Ru(bpy)(2)(HL)]Cl-2 have been prepared. Synthesized compounds have been structurally characterized by IR, H-1 NMR, LC-MS, fluorescence spectroscopy, elemental and thermal (TGA-DSC) analyses. The metal to the ligand ratio of the Ru(II) complex was found to be 1:1. Antifungal activities of the ligand and complex have been investigated. The Ru(II) complex have strong antifungal activity than the ligand against Aspergillus niger.