Oligomeric tetrathiafulvalenes: A new route toward conjugated TTF dimers and trimers


Gautier N., Samuel R., ŞAHİN Y. , Levillain E., Leroy-Lhez S., Hudhomme P.

ORGANIC LETTERS, vol.6, no.10, pp.1569-1572, 2004 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 6 Issue: 10
  • Publication Date: 2004
  • Doi Number: 10.1021/ol0496201
  • Title of Journal : ORGANIC LETTERS
  • Page Numbers: pp.1569-1572

Abstract

The synthesis of bis-TTF 1 and tris-TTF 2, linked by an ethenyl spacer, is described using new useful Wittig-type reagents with the introduction of phosphonate functionality on 1,3-dithiole and TTF frameworks. Electrochemical and spectroscopic studies show intramolecular electronic interactions between conjugated TTF units.