Oligomeric tetrathiafulvalenes: A new route toward conjugated TTF dimers and trimers

Gautier, N.; Samuel, R.; ŞAHİN, Yücel; Levillain, E; Leroy-Lhez, S.; Hudhomme, P.

doi:10.1021/ol0496201

Oligomeric tetrathiafulvalenes: A new route toward conjugated TTF dimers and trimers

Gautier N., Samuel R., ŞAHİN Y., Levillain E., Leroy-Lhez S., Hudhomme P.

ORGANIC LETTERS, cilt.6, sa.10, ss.1569-1572, 2004 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 6 Sayı: 10
Basım Tarihi: 2004
Doi Numarası: 10.1021/ol0496201
Dergi Adı: ORGANIC LETTERS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.1569-1572
Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The synthesis of bis-TTF 1 and tris-TTF 2, linked by an ethenyl spacer, is described using new useful Wittig-type reagents with the introduction of phosphonate functionality on 1,3-dithiole and TTF frameworks. Electrochemical and spectroscopic studies show intramolecular electronic interactions between conjugated TTF units.