Reactions of the dianion obtained by reductive metallation of 3,4-diphenylcinnoline


Ocal N., Turgut Z. , Kaban S.

MONATSHEFTE FUR CHEMIE, cilt.130, ss.915-920, 1999 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 130 Konu: 7
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1007/pl00010272
  • Dergi Adı: MONATSHEFTE FUR CHEMIE
  • Sayfa Sayısı: ss.915-920

Özet

The reductive metallation of 3,4-diphenylcinnoline (1) by sodium metal in tetrahydrofuran under an inert atmosphere to the monomeric dianion 2 has been explored, and the nucleophilicity of the disodium adduct towards various protonation, alkylation, and acylation reagents has been investigated. Generally, 2 reacts via its 1,4-positions forming 1,4-dihydro derivatives of 1.