3. International Conference on Life and Engineering Sciences (ICOLES 2020), İstanbul, Türkiye, 11 - 13 Aralık 2020, ss.1-9
Li-rich NiMnCo
(NMC)-based materials are used as cathode material due to the high energy
density and high voltage in lithium-ion batteries. One significant challenge is nested in adjusting their synthesis
conditions to reach optimum electrochemical performance and using green and
low-cost synthesis protocol. In study, Li1.2Ni0.20Co0.52Mn0.08O2 cathode material was synthesized
by using supercritical CO2 at low temperature (700°C) and low times (4h). Based on XRD, the synthesized sample has high purity and crystalline structure. The particle
size of synthesized sample at low temperature
is not uniform and an average size varies between 1 and 5 micron. Conversely,
the particle size of sample calcined at 900 °C is smaller than those of sample
calcined at 700 °C. The chemical structure of calcined sample was provided to
be Li1.2Ni0.20Co0.52Mn0.08O2
by EDS and ICP/OES. This work opens up a new avenue
for preparation of Li-rich NMC electrode materials via low-cost, simple and
green approach.