Determination of Thallium in Tea with Preconcentration by Microwave-Assisted Synthesized Molybdenum Disulfide Nanoparticles and Flame Atomic Absorption Spectrometry (FAAS) Analysis

Tışlı B., Gösterişli T., BAKIRDERE S.

Analytical Letters, cilt.57, sa.11, ss.1715-1726, 2024 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 57 Sayı: 11
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1080/00032719.2023.2266532
  • Dergi Adı: Analytical Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chemical Abstracts Core, Chimica, Communication Abstracts, Food Science & Technology Abstracts, Metadex, Veterinary Science Database, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1715-1726
  • Anahtar Kelimeler: Flame atomic absorption spectrometry (FAAS), microwave-assisted synthesized molybdenum disulfide nanoparticles, tea analysis, thallium
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A simple, quick and environmentally friendly microwave-assisted synthesis method was developed to produce MoS2 nanoparticles (MoS2NP) for the preconcentration of thallium. The characteristics of the synthesized MoS2NP were validated by x-ray diffraction (XRD) and scanning electron microscopy (SEM). The determination of thallium was achieved with MoS2NP based preconcentration and a flame atomic absorption spectrophotometer (MoS2NP-PM-FAAS). A detection limit of 14.6 µg/kg was achieved for thallium using the optimum conditions by the MoS2-PM-FAAS method. The developed method provided an improvement in the detection power of the FAAS system by approximately 20-fold. The applicability of the method was validated with tea samples through spike recovery experiments.