New ligand based on p-tertbutyltetrathiacalixarene blocked in
1,3-alternate conformation, was achieved via a multistep synthesis with
the introduction of thiomethylpropoxy groups on the lower rim which
leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalixarene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6
salt, leads to the formation of neutral, new 2-D coordination network,
which was structurally investigated in the solid state by X-ray
diffraction methods on a single crystal.