TURKISH JOURNAL OF CHEMISTRY, vol.46, no.5, pp.1541-1547, 2022 (SCI-Expanded)
New ligand based on p-tertbutyltetrathiacalix[4]arene blocked in
1,3-alternate conformation, was achieved via a multistep synthesis with
the introduction of thiomethylpropoxy groups on the lower rim which
leads to a neutral tecton. The combination of this p-tertbutyltetrathiacalix[4]arene (p-TCA-2), in 1, 3-alternate imposed conformation, with tetrahedral Ag(I)SbF6
salt, leads to the formation of neutral, new 2-D coordination network,
which was structurally investigated in the solid state by X-ray
diffraction methods on a single crystal.