Synthesis and characterization of a new imidazole ligand and its complexes with cobalt(II), nickel(II) and copper(II)


Erden I. , Demirhan N. , Avciata U.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.36, ss.559-562, 2006 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 36 Konu: 7
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1080/15533170600862762
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Sayfa Sayıları: ss.559-562

Özet

A new imidazole ligand, benzo[15-crown-5]-1H-imidazol [4,5-f][1,10] phenanthroline (bip) has been synthesized from the reaction of 5,6-diamino-1,10-phenanthroline with 4'-formyl-benzo-15-crown-5. The Co(II), Ni(II) and Cu(II) complexes of the ligand were prepared and characterized. The metal to the ligand ratio of the Co( II), Ni( II) and Cu( II) complexes was found to be 2: 1. The ligand and complexes have been characterized by FTIR, UV-visible, H-1 NMR, fluorescence spectrophotometer, elemental analyses and mass spectra.