Synthesis and characterization of a new imidazole ligand and its complexes with cobalt(II), nickel(II) and copper(II)

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Atıf İçin Kopyala

Erden I., Demirhan N., Avciata U.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.36, sa.7, ss.559-562, 2006 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 36 Sayı: 7
• Basım Tarihi: 2006
• Doi Numarası: 10.1080/15533170600862762
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.559-562
• Anahtar Kelimeler: imidazole, 1,10-phenanthroline, crown ether, CROWN-ETHERS, BINDING, METALS, SODIUM
• Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A new imidazole ligand, benzo[15-crown-5]-1H-imidazol [4,5-f][1,10] phenanthroline (bip) has been synthesized from the reaction of 5,6-diamino-1,10-phenanthroline with 4'-formyl-benzo-15-crown-5. The Co(II), Ni(II) and Cu(II) complexes of the ligand were prepared and characterized. The metal to the ligand ratio of the Co( II), Ni( II) and Cu( II) complexes was found to be 2: 1. The ligand and complexes have been characterized by FTIR, UV-visible, H-1 NMR, fluorescence spectrophotometer, elemental analyses and mass spectra.