Leaf–like copper–based nanocomposites as adsorbents for dispersive solid-phase extraction: application to determination of cobalt in lemon balm tea using FAAS

Yazıcı E., Ayyıldız M. F., Bodur S., BAKIRDERE S.

Journal of Nanoparticle Research, cilt.27, sa.8, 2025 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 27 Sayı: 8
  • Basım Tarihi: 2025
  • Doi Numarası: 10.1007/s11051-025-06391-2
  • Dergi Adı: Journal of Nanoparticle Research
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Biotechnology Research Abstracts, Compendex, INSPEC, Metadex
  • Anahtar Kelimeler: Cobalt, Dispersive solid phase extraction, Flame atomic absorption spectrometry, Health effects, Leaf-like copper-based nanocomposites, Lemon balm tea
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

This study proposed an analytical method named dispersive solid phase extraction–flame atomic absorption spectrometry (DSPE-FAAS) for the quantitation of cobalt in balm tea samples. Copper-based nanocomposites were used as adsorbent in the DSPE process. Influential DSPE parameters such as pH/volume of buffer solution, nanocomposite amount, sample volume, mixing type/period, and eluent concentration/volume were optimized to augment signal-to-noise ratio of cobalt. System analytical performance study for the DSPE-FAAS method was carried out, and limit of detection/quantitation (LOD/LOQ) values were recorded as 5.80 µg/kg and 19.33 µg/kg, with a relatively wide dynamic range (20.59 – 400.68 µg/kg). Spiked lemon balm tea samples were employed to perform recovery studies, and satisfactory recovery results were obtained between 76.7% and 128.1% via the external standard calibration method. According to the recorded recovery results, the proposed DSPE-FAAS method can be accurately applied to lemon balm tea samples in order to determine cobalt content.