Synthesis and Characterization of Metallophthalocyanines Containing Carboxylic Group

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KESER KARAOĞLAN G., Hışır A., GÜMRÜKÇÜ KÖSE G.

20. Frühjahrssymposium JungChemikerForum, Konstanz, Germany, 21 March 2018, pp.181

  • Publication Type: Conference Paper / Summary Text
  • City: Konstanz
  • Country: Germany
  • Page Numbers: pp.181
  • Yıldız Technical University Affiliated: Yes

Abstract

P98- Synthesis and Characterization of Metallophthalocyanines Containing Carboxylic Group

Gülnur Keser Karaoğlan (a)*, Arif Hışır (a), Gülşah Gümrükçü Köse (a)

a: Yildiz Technical University, Faculty of Arts & Science, Chemistry Department, Davutpasa, 34210, Istanbul, Turkey

email: gulnurkeser@hotmail.com

Phthalocyanines and their metallo derivatives (MPcs) have recently attracted an increasing interest not only for the preparation of dyes and pigments but also as building blocks for the construction of new molecular materials for electronics and optoelectronics. Numerous properties arise from their electronic delocalization, which makes them valuable in different fields of science and technology such as photoconducting agents in photocopying devices, chemical sensors, electrocatalyst, data storage systems, liquid crystals and photosensitizer in photodynamic therapy. [1-2] Dyestuffs containing carboxylic group are advantageous because they can be anchored onto the hydroxyl-bearing oxide surface. [3] Carboxyl-bearing metallophthalocyanines have been studied in terms of photophysical and photochemical properties in homogeneous solutions and in micellar systems. [4] In this work, our aim has been the synthesis of carboxylic acid containing metallophthalocyanines (MPc; M= Zn, Cu, Co) by cyclotetramerisation of the phthalonitrile and characterized by elemental analyses, FTIR, 1 H NMR, UV–vis and MALDITOF MS spectral data.

Acknowledgements This study was supported by Yildiz Technical University (Projects No: 2016-01-02-DOP03).

[1] Leznoff CC, Lever ABP. Phthalocyanines properties and applications. Weinheim: VCH Publishers; 1989.

[2] McKeown NB. Phthalocyanine materials: synthesis, structure and function. Cambridge: Cambridge University Press; 1998

[3] Í.A. de Carcer García, A.M. Sevim, A. de la Escosura, T. Torres, Org. Biomol. Chem., 2013, 11, 2237-2240.

[4] G.G. Matlou, N. Kobayashi, M. Kimura, T. Nyokong, New J. Chem., 2017, 41, 12309- 12318.