A facile synthesis of (+/-)-mintlactone


Tanyeli C., Caliskan Z. , Demir A. S.

SYNTHETIC COMMUNICATIONS, cilt.27, ss.3471-3476, 1997 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 27 Konu: 19
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1080/00397919708005649
  • Dergi Adı: SYNTHETIC COMMUNICATIONS
  • Sayfa Sayıları: ss.3471-3476

Özet

(+/-)-Mintlactone has been synthesized by applying a novel effective synthetic sequence. 4-Methylcyclohexanone was subjected to acetoxylation with Pb(OAc)(4). Hydrolysis followed by reaction with 2-chloroprogionyl chloride,then treatment with triethyl phosphite and, finally, Horner-Emmons-type intramolecular cyclization afforded (+/-)-Mintlactone.