1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts

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AKDAŞ KILIÇ H., Graf E., Hosseini M. W., Kyritsakas N.

Turkish Journal of Chemistry, cilt.46, sa.4, ss.1245-1252, 2022 (SCI-Expanded) identifier identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 4
  • Basım Tarihi: 2022
  • Doi Numarası: 10.55730/1300-0527.3431
  • Dergi Adı: Turkish Journal of Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.1245-1252
  • Anahtar Kelimeler: Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

© TÜBİTAK.The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.