1-D and 2-D coordination networks based on tetrathiacalix[4]arene derivative generated with mercury and cobalt salts

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AKDAŞ KILIÇ H., Graf E., Hosseini M. W., Kyritsakas N.

Turkish Journal of Chemistry, vol.46, no.4, pp.1245-1252, 2022 (SCI-Expanded) identifier identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 46 Issue: 4
  • Publication Date: 2022
  • Doi Number: 10.55730/1300-0527.3431
  • Journal Name: Turkish Journal of Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.1245-1252
  • Keywords: Molecular networks, coordination polymer, thiacalix[4]arene, X-ray structure
  • Yıldız Technical University Affiliated: Yes

Abstract

© TÜBİTAK.The combination of four iso-nicotinate appended tetrathiacalix[4]arene (TCA-1) in 1,2-alternate imposed conformation behaving as neutral tectons with Co(II)Cl2 and Hg(II)Cl2 metallic salts, leads to the formation of neutral, new coordination networks. Indeed, the tetrasubstituted TCA-1 derivative leads to a 1D coordination polymer with Co(II)Cl2 and a 2D grid-like network with, Hg(II)Cl2. The effect of the nature of the metal used on the dimensionality was demonstrated by X-ray diffraction studies on a single crystal.