The Synthesis of 2,6-Pyridinedicarboxylic Acid Modified Porous Polypyrrole Electrodes and Its Energy Storage Application

ARVAS M. B., YAZAR AYDOĞAN S., ŞAHİN Y.

ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, cilt.11, sa.11, 2022 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 11 Sayı: 11
  • Basım Tarihi: 2022
  • Doi Numarası: 10.1149/2162-8777/aca17c
  • Dergi Adı: ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Compendex, INSPEC
  • Anahtar Kelimeler: polypyrrole, dicarboxylic acid, porous electrode structure, hydrothermal synthesis, supercapacitor, energy storage, CARBON NANOTUBE, SUPERCAPACITOR, PERFORMANCE, COMPOSITES, FILMS, CONDUCTIVITY, MORPHOLOGY, SULFONATE
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

The well-designed porous polypyrrole/dicarboxylic acid (PPy/DCA) (0.02) electrodes were successfully synthesized by hydrothermal method. In this study, the interesting structural properties of the synthesized electrodes were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analysis (TG-DTA), Brunauer-Emmett-Teller (BET) and scanning electron microscopy (SEM). The scanning electron microscopy results showed that a large number of random pores were formed on the electrode surface during the polymerization of pyrrole. The galvanostatic charge-discharge measurements exhibited a specific capacity of 854.2 F.g(-1) at 2.7 A.g(-1) with an energy density of 884.4 Wh.kg(-1). Further, the supercapacitor electrode showed a good cycling test (87.3%) after 4000 cycles at a current density of 10.0 A.g(-1) and wide operating voltage (3.0 V). Our studies suggest that 2,6-pyridinedicarboxylic acid doped-polypyrrole electrodes with interesting structure and easy synthesized method are promising candidates for high-performance supercapacitor devices.