Electronic energy levels of CsCdCl3

Demirbilek R., BOZDOĞAN A., ÇALIŞKAN M., Asan G., Ozen G.

JOURNAL OF LUMINESCENCE, cilt.131, sa.9, ss.1853-1856, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 131 Sayı: 9
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.jlumin.2011.05.003
  • Dergi Adı: JOURNAL OF LUMINESCENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1853-1856
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

The excitation and emission spectra of CsCdCl3 crystal grown by the Bridgman growth technique, are observed. Its dominant excitation spectra correspond to the transitions between the electronic energy levels of the face-shared [CdCl6](4-) octahedron complexes with C-3v symmetry. With the help of the molecular orbital diagram of the [CdCl6](4-) molecule complex, an approximate electronic energy level diagram of this crystal is constructed using one-electron approximation. (C) 2011 Elsevier B.V. All rights reserved.