Electronic energy levels of CsCdCl3


Demirbilek R. , BOZDOĞAN A., ÇALIŞKAN M. , Asan G., Ozen G.

JOURNAL OF LUMINESCENCE, cilt.131, ss.1853-1856, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 131 Konu: 9
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.jlumin.2011.05.003
  • Dergi Adı: JOURNAL OF LUMINESCENCE
  • Sayfa Sayıları: ss.1853-1856

Özet

The excitation and emission spectra of CsCdCl3 crystal grown by the Bridgman growth technique, are observed. Its dominant excitation spectra correspond to the transitions between the electronic energy levels of the face-shared [CdCl6](4-) octahedron complexes with C-3v symmetry. With the help of the molecular orbital diagram of the [CdCl6](4-) molecule complex, an approximate electronic energy level diagram of this crystal is constructed using one-electron approximation. (C) 2011 Elsevier B.V. All rights reserved.