Synthesis and Characterization of Polyphosphonates and Polyurethanes Using Chalcone and DOPO-Chalcone as a Flame Retardant


Cetinkaya I. C. , Yuksel G., Macit C., ÜREYEN M. E. , EREN T.

ACS APPLIED POLYMER MATERIALS, vol.3, no.10, pp.5277-5290, 2021 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 3 Issue: 10
  • Publication Date: 2021
  • Doi Number: 10.1021/acsapm.1c01054
  • Title of Journal : ACS APPLIED POLYMER MATERIALS
  • Page Numbers: pp.5277-5290
  • Keywords: chalcone, DOPO, polyphosphonates, polyurethanes, flame retardants, fire mechanism, EPOXY-RESINS, PHOSPHORUS, MECHANISM, PHOSPHAPHENANTHRENE, DERIVATIVES, TOXICITY, MICHAEL, OIL

Abstract

We synthesized a series of chalcone-based polyphosphonates and polyurethanes as self-extinguishing flame-retardant polymers and characterized them via FTIR,H- 1, C-13 ,P-31 NMR, HRMS, gel permeation chromatography, and inductively coupled plasma-optical emission spectrometry. The thermal stability of the synthesized polymer series was tested by thermogravimetric and evolved gas analysis under both N-2 and air atmospheres as well as microscale combustion calorimetry analysis. After thermal treatment, residue analysis was carried out using scanning electron microscopy with energy-dispersive X-ray analysis and X-ray photoelectron spectroscopy, and decomposition mechanisms are proposed.