Influence of high-temperature ECAP on the structure and mechanical properties of a biodegradable Zn-Cu-Mn alloy for medical implants Влияние высокотемпературного РКУП на структуру и механические свойства биодеградируемого сплава Zn-Сu-Mn для медицинских имплантов
Frontier Materials and Technologies, cilt.2026, sa.1, ss.9-18, 2026 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 2026 Sayı: 1
- Basım Tarihi: 2026
- Doi Numarası: 10.18323/2782-4039-2026-1-75-1
- Dergi Adı: Frontier Materials and Technologies
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.9-18
- Anahtar Kelimeler: biocompatibility, biocompatible alloys, biodegradable metals, ECAP, equal-channel angular pressing, mechanical properties, transmission electron microscopy, ureteral stents, zinc alloys, Zn-Cu-Mn
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
Problem. Currently used materials for ureteral stents are unable to eliminate inflammation, exhibit low strength, and require a second surgery for removal. Metallic bioresorbable stents can reduce the burden on the patient’s body and eliminate additional operations for product removal. Aim. To produce a new biocompatible Zn-1 %Cu-1 %Mn alloy and, using equal-channel angular pressing at elevated temperature, to develop an improved set of mechanical properties for potential application as a material for ureteral stents. Methods. The Zn-1 %Cu-1 %Mn alloy was subjected to equal-channel angular pressing at 200°C (8 passes, route Bc). The microstructure and elemental composition were studied using transmission electron microscopy w ith energy-dispersive analysis. Mechanical properties were evaluated under uniaxial tension (strain rate of 10–3 s–1, at least 3 samples per each condition), Vickers microindentation with construction of hardness distribution maps, and fractographic analys is of fracture surfaces using a scanning electron microscope. Results. By indexing diffraction patterns, it was established that the deformation processing promotes the precipitation of MnZn13 phase particles, which may have a strengthening effect. Fractographic analysis of fractured samples after tension showed a change in the fracture character from brittle to ductile with deep dimples. Carrying out equal-channel angular pressing (ECAP) for 8 passes at elevated temperatures allowed increasing the ultimate tensile strength by 2.3 times, the offset yield strength by 3 times, and the percentage elongation by 8 times. The distribution of microhardness values becomes more uniform with an increase in passes from 2 to 8, and the gap between the smallest and largest values decreases. Conclusions. It was established that the deformation method (ECAP, 8 passes) for the new biocompatible Zn-1 %Cu-1 %Mn alloy develops an improved set of mechanical properties, which opens up possibilities for its application in medica l purposes.