Influence of high-temperature ECAP on the structure and mechanical properties of a biodegradable Zn-Cu-Mn alloy for medical implants Влияние высокотемпературного РКУП на структуру и механические свойства биодеградируемого сплава Zn-Сu-Mn для медицинских имплантов


Creative Commons License

Abdrakhmanova E. D., Khafizova E. D., Polenok M. V., Islamgaliev R. K., Li Z., Li L., ...Daha Fazla

Frontier Materials and Technologies, cilt.2026, sa.1, ss.9-18, 2026 (Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 2026 Sayı: 1
  • Basım Tarihi: 2026
  • Doi Numarası: 10.18323/2782-4039-2026-1-75-1
  • Dergi Adı: Frontier Materials and Technologies
  • Derginin Tarandığı İndeksler: Scopus
  • Sayfa Sayıları: ss.9-18
  • Anahtar Kelimeler: biocompatibility, biocompatible alloys, biodegradable metals, ECAP, equal-channel angular pressing, mechanical properties, transmission electron microscopy, ureteral stents, zinc alloys, Zn-Cu-Mn
  • Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

Problem. Currently used materials for ureteral stents are unable to eliminate inflammation, exhibit low strength, and require a second surgery for removal. Metallic bioresorbable stents can reduce the burden on the patient’s body and eliminate additional operations for product removal. Aim. To produce a new biocompatible Zn-1 %Cu-1 %Mn alloy and, using equal-channel angular pressing at elevated temperature, to develop an improved set of mechanical properties for potential application as a material for ureteral stents. Methods. The Zn-1 %Cu-1 %Mn alloy was subjected to equal-channel angular pressing at 200°C (8 passes, route Bc). The microstructure and elemental composition were studied using transmission electron microscopy w ith energy-dispersive analysis. Mechanical properties were evaluated under uniaxial tension (strain rate of 10–3 s–1, at least 3 samples per each condition), Vickers microindentation with construction of hardness distribution maps, and fractographic analys is of fracture surfaces using a scanning electron microscope. Results. By indexing diffraction patterns, it was established that the deformation processing promotes the precipitation of MnZn13 phase particles, which may have a strengthening effect. Fractographic analysis of fractured samples after tension showed a change in the fracture character from brittle to ductile with deep dimples. Carrying out equal-channel angular pressing (ECAP) for 8 passes at elevated temperatures allowed increasing the ultimate tensile strength by 2.3 times, the offset yield strength by 3 times, and the percentage elongation by 8 times. The distribution of microhardness values becomes more uniform with an increase in passes from 2 to 8, and the gap between the smallest and largest values decreases. Conclusions. It was established that the deformation method (ECAP, 8 passes) for the new biocompatible Zn-1 %Cu-1 %Mn alloy develops an improved set of mechanical properties, which opens up possibilities for its application in medica l purposes.