Akademik Veri Yönetim Sistemi
CHEMISTRYSELECT, cilt.15, sa.10:e06905, ss.1-15, 2025 (Scopus)
Polyaminoboranes, as inorganic analog of polyolefins, can be used to synthesize organic–inorganic hybrid ceramics, known asceramers, and are typical examples of inorganic polymers. Here, p block elements, such as boron (B), silicon (Si), and phosphorus(P) possessing polyaminoborane homopolymers, were synthesized and characterized. After the synthesis of phosphorus–boraneand amino silicon–borane complexes, polyaminoborane derivatives were obtained dehydrocoupling reaction in the presenceof Grubbs catalyst. Boron nitride–phosphorus (P–BN) and boron nitride–silicon (Si–BN)-based ceramics were obtained underpyrolysis condition using polyaminoborane precursors. To demonstrate surface coating application, carbon fiber surface wasdip-coated with polyaminoborane derivatives and pyrolyzed to get the functional boron nitride coating on the carbon fiber surface