Preparation and Characterization of Boron Nitride Coatingson Carbon Fibers From Functionalized Polyaminoboranes
CHEMISTRYSELECT, cilt.15, sa.10:e06905, ss.1-15, 2025 (Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 15 Sayı: 10:e06905
- Basım Tarihi: 2025
- Doi Numarası: 10.1002/slct.202506905
- Dergi Adı: CHEMISTRYSELECT
- Derginin Tarandığı İndeksler: Scopus
- Sayfa Sayıları: ss.1-15
- Açık Arşiv Koleksiyonu: AVESİS Açık Erişim Koleksiyonu
- Yıldız Teknik Üniversitesi Adresli: Evet
Özet
Polyaminoboranes, as inorganic analog of polyolefins, can be used to synthesize organic–inorganic hybrid ceramics, known asceramers, and are typical examples of inorganic polymers. Here, p block elements, such as boron (B), silicon (Si), and phosphorus(P) possessing polyaminoborane homopolymers, were synthesized and characterized. After the synthesis of phosphorus–boraneand amino silicon–borane complexes, polyaminoborane derivatives were obtained dehydrocoupling reaction in the presenceof Grubbs catalyst. Boron nitride–phosphorus (P–BN) and boron nitride–silicon (Si–BN)-based ceramics were obtained underpyrolysis condition using polyaminoborane precursors. To demonstrate surface coating application, carbon fiber surface wasdip-coated with polyaminoborane derivatives and pyrolyzed to get the functional boron nitride coating on the carbon fiber surface