One step hydroxybromination of fatty acid derivatives


Eren T. , KUSEFOGLU S.

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, cilt.106, ss.27-34, 2004 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 106 Konu: 1
  • Basım Tarihi: 2004
  • Doi Numarası: 10.1002/ejlt.200300869
  • Dergi Adı: EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
  • Sayfa Sayısı: ss.27-34

Özet

Hydroxybromination of methyl oleate, oleic acid and new sunflower oil (high oleic), in an acetone/water mixture by a one step reaction using N-bromosuccinimide, was studied. The yield of bromohydrin products from oleic acid, methyl oleate and sunflower oil were 90%, 78% and 40%, respectively. Reaction products were analyzed by H-1 and C-13 nuclear magnetic resonance spectroscopy, infrared spectroscopy, gas chromatography, and mass spectrometry. The hydrobromide derivative of new sunflower oil was acrylated and polymerized to a new polymer.