Novel phthalocyanines with naphthalenic substituents


ŞENER M. K. , Guel A., Kocak M. B.

TRANSITION METAL CHEMISTRY, cilt.33, ss.867-872, 2008 (SCI İndekslerine Giren Dergi)

  • Cilt numarası: 33 Konu: 7
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1007/s11243-008-9125-4
  • Dergi Adı: TRANSITION METAL CHEMISTRY
  • Sayfa Sayısı: ss.867-872

Özet

Phthalocyanines with four naphthyl-malonic ester groups on the periphery were synthesized by cyclotetramerization of 4-(1,1-dicarbethoxy-2-(1-naphthyl)-ethyl)-phthalonitrile. The new compounds were characterized by spectroscopic methods. The electronic spectra exhibit intense pi-pi* transitions from the naphthyl moiety together with the characteristic Q and B bands of the phthalocyanine core. The electrochemical properties of the 2,9,17,23-tetra-(1,1-(dicarbethoxy)-2-(1-naphthyl)-ethyl) phthalocyaninato copper(II) complex were studied by cyclic voltammetry.