Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation

Akdas, Huriye; Graf, E; Hosseini, MW; De Cian, A; Harrowfield, JM

doi:10.1039/b007761p

Design, synthesis and structural investigation of a 2-D coordination network based on the self-assembly of the tetracarboxylate derivative of tetrathiacalix[4]arene and silver cation

Akdas H., Graf E., Hosseini M., De Cian A., Harrowfield J.

CHEMICAL COMMUNICATIONS, sa.22, ss.2219-2220, 2000 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 2000
Doi Numarası: 10.1039/b007761p
Dergi Adı: CHEMICAL COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.2219-2220
Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The fully deprotonated tetrathiacalix[4]arene 1(4-) in 1,3-alternate conformation and bearing four carboxylate units was shown to act as a tecton leading, in the presence of Ag+ cation, to a 2-D coordination network in the crystalline phase which can be described as discrete binuclear [1(4-), (Ag+)(2)](2-) complexes interconnected by Ag+ cations.