Macrocyclic Cu(II)-organophosphonate building block with room temperature magnetic ordering
DALTON TRANSACTIONS, vol.44, no.28, pp.12526-12529, 2015 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 44 Issue: 28
- Publication Date: 2015
- Doi Number: 10.1039/c5dt01596k
- Journal Name: DALTON TRANSACTIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.12526-12529
- Yıldız Technical University Affiliated: Yes
Abstract
Engineering a copper coordination sphere with organoimine ligands and tuning the organophosphonate protonation states produced[{Cu(2,2'-bpy)}(2)(HO3P(CH2)(8)PO3H2)(4)] (1) and [{Cu(terpy)}(2)-(2,7-FDA-H-2)(2)]center dot(2,7-FDA-H-4)(2H(2)O) (2) (2,7-FDA-H-4 = 2,7-fluore-nonediphosphonic acid) macrocyclic copper-organophosphonate building blocks. 1 exhibits high temperature magnetic ordering, while 2 is paramagnetic. The structures were characterized by single crystal X-ray diffraction.