Syntheses of 1,3-bis(2-arylimino)isondoline type ligands and some metal complexes containing EDOT moiety


Göktuğ O., Korkut S., Gökçe B. N., Tekbasoglu T. Y., Sener K.

MAIN GROUP CHEMISTRY, vol.17, no.4, pp.293-299, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 17 Issue: 4
  • Publication Date: 2018
  • Doi Number: 10.3233/mgc-180671
  • Journal Name: MAIN GROUP CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.293-299
  • Yıldız Technical University Affiliated: Yes

Abstract

EDOT (3,4-ethylenedioxythiophene) substituted 1,3-bis(2-arylimino)isoindoline derivatives EDOT-BAI1, EDOT-BAI2, EDOT-BAI3, and EDOT-BAI4 have been synthesized according to the Linstead or Siegl's method. Preparation of palladium(II) and platinum(II) complexes of EDOT-BAI1 and EDOT-BAI2 have been also accomplished in this study. The new compounds have been characterized by FT-IR, NMR, UV-Vis spectroscopies and via mass spectrometric analysis. The present EDOT derivatives provide new starting materials that may be useful in the synthesis of new, functional electropolymers.