Synthesis and characterisation of D-n-D type Schiff base ligands derived from fluorene and 1,10-phenanthroline and its complexes with ruthenium(ll)


Elmali F. T. , ERDEN İ., DEMİRHAN N., AVCIATA U.

Journal of Chemical Research, no.2, pp.90-92, 2009 (Peer-Reviewed Journal) identifier

  • Publication Type: Article / Article
  • Publication Date: 2009
  • Journal Name: Journal of Chemical Research
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.90-92
  • Keywords: 1,10- phenanthroline, Complex, D-π-D, Fluorene, Schiff base

Abstract

A fluorene derivative, 9H-fluoren-9-one(diphenylmethylene)hydrazone has been synthesised from the reaction of 4,5-diazafluoren-9-one with benzophenone hydrazone and a 1,10-phenanthroline derivative, N-[(1E,2E)-3-phenylprop-2-en-1- ylidene]-1,10-phenanthrolin-5-amine has been synthesised from the reaction of 5-amino-1,10-phenanthroline with cinnamaldehyde. Ru(ll) complexes of these ligands have been prepared and characterised.