Sulfur-nitrogen heterocycles from the condensation of pyrazolones and 2-iminothiazolidin-4-ones with phenyl isothiocyanate

Bagdatli E., Akkus S., YOLAÇAN Ç., Oecal N.

JOURNAL OF CHEMICAL RESEARCH, sa.5, ss.302-304, 2007 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Basım Tarihi: 2007
  • Dergi Adı: JOURNAL OF CHEMICAL RESEARCH
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.302-304
  • Yıldız Teknik Üniversitesi Adresli: Evet

Özet

The condensation of 2-pyrazolin-5-ones with phenyl isothiocyanate, followed by reaction of the resulting thiolate ions with chloroacetyl chloride, phenacyl bromide, oxalyl chloride, 1,4-dibromo-2,3-butanedione and ethyl chloroformate, resulted in cyclisation to S,N-heterocycles in all cases. 2-Iminothiazolidin-4-ones, with phenyl isothiocyanate and then chloroacetyl chloride or phenacyl bromide, similarly formed 2,4 '-bi(thiazolidine)-derived products.