Spectra and relaxation of electronic excitations in CsCdBr3 : Yb3+ and CsCdBr3 : Nd3+ monocrystals


Gafurov M., Iskhakova A., Kurkin I., Kurzin S., Malkin B., Nikitin S., ...Daha Fazla

11th Feofilov Workshop on Spectroscopy of Crystals Activated by Rare-Earth and Transition-Metal Ions, Kazan, Rusya, 24 - 28 Eylül 2001, cilt.4766, ss.279-291 identifier identifier

  • Cilt numarası: 4766
  • Doi Numarası: 10.1117/12.475344
  • Basıldığı Şehir: Kazan
  • Basıldığı Ülke: Rusya
  • Sayfa Sayıları: ss.279-291

Özet

Experimental and theoretical studies of the optical and EPR spectra, and the spin-lattice relaxation in CsCdBr3 crystals containing 0.1, 0.3 and 1.0 mol.% of impurity Yb3+ ions have been fulfilled. In the optical excitation spectrurn, a broad charge transfer band has been detected in the wave-number range of 25000-35000 cm(-1). The hybridization of the excited electron configuration corresponding to the charge transfer from the ligand (Br) 4p closed shells on the ground 4f(13) configuration of the ytterbium ion is considered to interpret the anomalously large crystal field splitting of the F-2(5/2) multiplet. The EPR spectra with comparable intensities of the axial single-ion and symmetric dimer centres in the sample containing 0.3 mol.% of impurity Yb3+ ions were observed. Spin-lattice relaxation rates and linewidths in the EPR spectra of the single-ion and dimer centres were measured in the temperature range of 1.5 - 35 K at the frequency of 9.5 GHz at different directions of the applied magnetic field relative to the crystal symmetry axis. Experimental results are analyzed in the framework of the microscopic theory of the electron-phonon interaction with taking into account peculiarities of the phonon spectrum of the impurity CsCdBr3 lattice.