Thiacalixarenes: Synthesis and structural analysis of thiacalix[4]arene and of p-tert-butylthiacalix[4]arene

Akdas, Huriye; Bringel, L; Graf, E; Hosseini, MW; Mislin, G; Pansanel, J; De Cian, A; Fischer, J

doi:10.1016/s0040-4039(98)00067-7

Thiacalixarenes: Synthesis and structural analysis of thiacalix[4]arene and of p-tert-butylthiacalix[4]arene

Akdas H., Bringel L., Graf E., Hosseini M., Mislin G., Pansanel J., ...Daha Fazla

TETRAHEDRON LETTERS, cilt.39, sa.16, ss.2311-2314, 1998 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 39 Sayı: 16
Basım Tarihi: 1998
Doi Numarası: 10.1016/s0040-4039(98)00067-7
Dergi Adı: TETRAHEDRON LETTERS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.2311-2314
Yıldız Teknik Üniversitesi Adresli: Hayır

Özet

The synthesis of tetrathiacalix[4]arene was achieved by the detertiobutylation of p-tert-butyltetrathiacalix[4]arene. X-ray diffraction studies revealed that in the solid state whereas p-tert-butyltetrathiacalix[4]arene forms inclusion complexes with solvent molecules, tetrathiacalix[4]arene undergoes self-inclusion leading to trimeric units. The same behaviour in the crystalline phase was also demonstrated for calix[4]arene. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.