The Synthesis, Spectroscopic, Fluorescence, and Thermal Properties of a 1,10-phenanthroline Containing Derivative of Phenoxycyclotriphosphazene and its Ru(II) Complex


Kecin I., Elmali F. , DEMİRHAN N.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, vol.41, no.1, pp.1-7, 2011 (Journal Indexed in SCI) identifier identifier

  • Publication Type: Article / Article
  • Volume: 41 Issue: 1
  • Publication Date: 2011
  • Doi Number: 10.1080/15533174.2010.522666
  • Journal Name: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded, Scopus
  • Page Numbers: pp.1-7
  • Keywords: 1, 10-phenanthroline, cyclotriphosphazene, Ru complex, BENZYLCYANIDE SPACER, POLYPHOSPHAZENES, RUTHENIUM, CHEMISTRY, LIGAND

Abstract

A new phenoxycyclotriphosphazene derivative ligand, 2-chloro -2-salicylideneimino-1,10-phenanthrolino-4,4,6,6-bis[spiro(2',2''-dioksi-1',1''-bifenil)]cyclotriphosp- hazane (CS-CP), has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxybiphenyl)] cyclotriphosphazane and 5-salicylideneimino-1,10-phenanthroline and Ru(II) complex of this ligand has been prepared. The newly synthesized compounds have been verified by FTIR,1H NMR, 31P NMR, UV-vis., mass, and fluorescence spectra, together with elemental and thermal analysis.