The Synthesis, Spectroscopic, Fluorescence, and Thermal Properties of a 1,10-phenanthroline Containing Derivative of Phenoxycyclotriphosphazene and its Ru(II) Complex


Kecin I., Elmali F. , DEMİRHAN N.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.41, ss.1-7, 2011 (SCI İndekslerine Giren Dergi) identifier identifier

  • Cilt numarası: 41 Konu: 1
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1080/15533174.2010.522666
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Sayfa Sayıları: ss.1-7

Özet

A new phenoxycyclotriphosphazene derivative ligand, 2-chloro -2-salicylideneimino-1,10-phenanthrolino-4,4,6,6-bis[spiro(2',2''-dioksi-1',1''-bifenil)]cyclotriphosp- hazane (CS-CP), has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxybiphenyl)] cyclotriphosphazane and 5-salicylideneimino-1,10-phenanthroline and Ru(II) complex of this ligand has been prepared. The newly synthesized compounds have been verified by FTIR,1H NMR, 31P NMR, UV-vis., mass, and fluorescence spectra, together with elemental and thermal analysis.