The Synthesis, Spectroscopic, Fluorescence, and Thermal Properties of a 1,10-phenanthroline Containing Derivative of Phenoxycyclotriphosphazene and its Ru(II) Complex

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Atıf İçin Kopyala

Kecin I., Elmali F., DEMİRHAN N.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.41, sa.1, ss.1-7, 2011 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 41 Sayı: 1
• Basım Tarihi: 2011
• Doi Numarası: 10.1080/15533174.2010.522666
• Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1-7
• Anahtar Kelimeler: 1, 10-phenanthroline, cyclotriphosphazene, Ru complex, BENZYLCYANIDE SPACER, POLYPHOSPHAZENES, RUTHENIUM, CHEMISTRY, LIGAND
• Yıldız Teknik Üniversitesi Adresli: Evet

Özet

A new phenoxycyclotriphosphazene derivative ligand, 2-chloro -2-salicylideneimino-1,10-phenanthrolino-4,4,6,6-bis[spiro(2',2''-dioksi-1',1''-bifenil)]cyclotriphosp- hazane (CS-CP), has been synthesized from the reaction of 2,2-dichloro-4,4,6,6-bis[spiro(2',2''-dioxybiphenyl)] cyclotriphosphazane and 5-salicylideneimino-1,10-phenanthroline and Ru(II) complex of this ligand has been prepared. The newly synthesized compounds have been verified by FTIR,1H NMR, 31P NMR, UV-vis., mass, and fluorescence spectra, together with elemental and thermal analysis.